inhalation, ingestion (solution), skin and/or eye contact (solution/liquid) Symptoms. Serious Eye Damage/Eye Irritation Category 1. << Ammonium hydroxide is not a flammable liquid; however, ammonia gas is flammable. AMMONIUM HYDROXIDE reacts exothermically with acids. As a result, ammonium hydroxide is a severe eye, skin, and respiratory tract irritant, and readily burns tissue with which it comes in contact. Skin Corrosion/irritation Category 1 B. <<0E3A66ABCCE85E48B6E7192D2C7FA130>]>> Workers in all industries should know that, despite its common usage, ammonia poses health risks and hazards that require proper use of personal protective equipment (PPE) and safe use and handling procedures. Although the name ammonium hydroxide suggests an alkali with composition [NH 4 +][OH −], it is actually impossible to isolate samples of NH 4 OH. 0000003577 00000 n 0000000016 00000 n Level of Concern . Toxic by all routes (ie, inhalation, ingestion, and dermal contact), exposure to this colorless, intensely pungent-smelling liquid may occur from its use in fertilizers, dyes, explosives, plastics, cleansing agents, fibers, and resins. The vapors are extremely irritating to the eyes. Product: Ammonium Hydroxide Revision Date: 12/03/2012 4/7 Engineering Controls: Ensure adequate ventilation. SAFETY DATA SHEET: AMMONIUM CHLORIDE - AMMONIUM HYDROXIDE BUFFER TS AMMONIUM CHLORIDE - AMMONIUM HYDROXIDE BUFFER TS A631.7A INTEGRA Chemical Company 24 Hour Emergency Response: CHEMTREC 800 … Print Share on: Evidence. 0000018450 00000 n Source. 0000004534 00000 n This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200). AMMONIA SOLUTION, STRONG, AMMONIA WATER, AMMONIA, AQUEOUS SOLUTION, AMMONIUM HYDROXIDE, AMMONIUM HYDROXIDE ((NH4)(OH)), AQUA AMMONIUM, HARTSHORN SPIRIT, SPIRIT OF HARTSHORN, and STRONG AMMONIA SOLUTION 0000010276 00000 n %%EOF Reacts extremely violently with dimethyl sulfate [NFPA 491M 1991]. AMMONIUM HYDROXIDE can be found in 65 products. <> 0000018893 00000 n Ammonia: LC50, Water Flea (Daphnia magna): 0.66 mg/L 48 h Persistence and Degradability: Expected to be readily biodegradable. Exposure Routes. decomposition products. 0000013231 00000 n When dissolved in water, Ammonia forms Ammonium Hydroxide (H5NO). Tel: (201) 796-7100. Y>ákî'ÅI9‰bÀrR/OÕIÚϒ‡à÷+aoÁ¶’ßï? Environmental Effects: Very toxic to aquatic life. 61 0 obj <>stream : with (some) halogens compounds, with … ... in this product - not the product itself - compared to other product formulations. 0000004083 00000 n 0000001520 00000 n Product Name: Ammonium Hydroxide (10% to 30%) Synonyms: Ammonium Hydroxide Solutions, Aqua Ammonia, Aqua Ammonia Solutions, Ammonia Solutions, Ammonia Aqueous, Ammonia Water CAS REGISTRY NO: 1336-21-6 Supplier: Tanner Industries, Inc. 735 Davisville Road, Third Floor Southampton, PA 18966 Website: www.tannerind.com Telephone (General): 215-322-1238 P264 - Wash exposed skin thoroughly after handling. Health issue . 4 0 obj However concentrated ammonia solutions may give off ammonia vapours. Health Hazard Ammonium hydroxide solutions are alkaline solutions, meaning they have high pH level. It can be denoted by the symbols NH 3 (aq). stream Ammonium Hydroxide / 1336-21-6 39.1% 25 ppm TWA Water / 7732-18-5 60.9% 35 ppm STEL 50 ppm PEL Contains 19% ammonia as NH3 300 ppm IDLH 3. It is also a highly corrosive chemical and a skin, eye, and respiratory irritant. It is corrosive to metals and tissue. 0000002525 00000 n Used in everything from household cleaners to industrial processes, it is toxic in all solutions. On burning: release of toxic and corrosive gases/vapours (nitrous vapours). 7732-18-5), 98-99% Section 4: First Aid Measures Safety Data Sheet Ammonium Hydroxide Issue Date: 12/30/2015 V1.0 1. Ammonium hydroxide, ACS reagent, 28-30% solution in water, ACROS Organics™ CAS=1336-21 … Ammonia and Ammonium Hydroxide are used in a large variety of products including hair dyes, hair bleaching products, shaving cream and hair grooming products. Linear Formula NH 4 OH . Causes severe skin burns and eye damage. %���� Very toxic to aquatic life . P270 - Do not eat, drink or smoke when using this product. X���`I�%&/m�{J�J��t��`$ؐ@������iG#)�*��eVe]f@�흼��{���{���;�N'���?\fdl��J�ɞ!���?~|? Possibility of Hazardous Reactions Ammonium hydroxide will react exothermically with acids. Material uses: Laboratory Reagent. Ammonia vapors are released when heated. %PDF-1.4 Ammonium hydroxide is highly toxic whether it is inhaled, ingested, or absorbed through the skin. HAZARDS IDENTIFICATION Terra Industries Inc. Terra Centre – 600 Fourth Street Sioux City, Iowa … 0000001926 00000 n 0000001700 00000 n The following acute (short-term) health effects may occur immediately or shortly after exposure to Ammonium Hydroxide: fContact can severely irritate and burn the skin and eyes leading to eye damage. Conditions to Avoid Avoid ammonium hydroxide contact with chlorine, which forms a chloramine gas, which is a primary skin irritant and sensitizer. Company. Revised on 04/21/2016 Page 1 of 6 Safety Data Sheet Ammonium Hydroxide 3N 1. Ammonia vapor, in concentrations of 16-25% volume by weight in air, is flammable, toxic by inhalation and corrosive. Ammonium hydroxide itself is non-combustible. Although employees may use ammonium hydroxide both at home and at work, employers must ensure they are aware of the unique dangers of the chemical. 0000019076 00000 n MDL number MFCD00066650 0000004611 00000 n '’ü¸Š¥q When employees work with industrial chemicals, they often are not using products they will find at home. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls 0000001439 00000 n Fair Lawn, NJ 07410. It is soluble in water. %PDF-1.6 %âãÏÓ Ammonium hydroxide is a colorless liquid with a strong odor and bad taste. 0 Ammonia gas is generally not considered a serious fire or explosion hazard because ammonia/air mixtures are difficult endstream endobj 29 0 obj <. 0000009368 00000 n 1 0 obj Ventilation rates should be matched to conditions. Tetramethylammonium hydroxide (TMAH or TMAOH) is a quaternary ammonium salt with the molecular formula N(CH 3) 4 + OH −.It is commonly encountered as concentrated solutions in water or methanol.The solid and solutions are colorless, or yellowish if impure. 3 Effective date : 11.05.2014 Page 2 of 6 Ammonium Hydroxide, 3M Created by Global Safety Management, Inc. -Tel: 1-813-435-5161 - www.gsmsds.com Wear appropriate protective clothing to … 0000018685 00000 n 2.4. 0000004305 00000 n One Reagent Lane. 0000006157 00000 n 0000011267 00000 n *Please select more than one item to compare Fisher Scientific. The major hazards encountered in the use and handling of ammonium hydroxide stem from its toxicologic properties. Beilstein/REAXYS Number 3587154 . May cause respiratory irritation. Tetramethylammonium hydroxide is a solid in the hydrated form or a colorless liquid with a strong ammonia -like odor. 0000001303 00000 n Ammonia can be mixed with water and sold as ammonium hydroxide, or used in compressed gas as anhydrous ammonia (meaning without water). Safety Data Sheet according to 29CFR1910/1200 and GHS Rev. Take all appropriate precautions. Compliant with the OSHA Hazard Communication Standard 1910.1200 and aligned with the Globally Harmonized System of Classification and Labeling of Chemicals (GHS) Made in the United States of America P271 - Use only outdoors or in a well-ventilated area. 0000002366 00000 n Such a precipitate can explode on stirring [MCA Case History 1554 1968]. Avoid ammonium hydroxide contact with chemicals such as mercury, chlorine, iodine, bromine, silver oxide or hypochlorites; they can form explosive compounds. 0000019272 00000 n 0000003840 00000 n Evolves toxic gaseous ammonia with strong bases. As the nation's health protection agency, CDC saves lives and protects people from health, safety, and security threats. Ammonium hydroxide solution ACS reagent Synonym: Ammonia aqueous, Ammonia water CAS Number 1336-21-6. However, ammonium hydroxide is one exception. 0000005636 00000 n 0000008433 00000 n 0000012304 00000 n Compare Products: Select up to 4 products. Unknown Acute Toxicity (GHS-US) No data available. fInhaling Ammonium Hydroxidecan irritate the lungs causing coughing and/or shortness of breath. 28 34 startxref For use on containers that store Ammonium Hydroxide to ensure the workplace is aware of the immediate chemical hazards that are present. Box 219, Batavia, IL 60510 (800) 452-1261 Chemtrec Emergency Phone Number: (800) 424-9402 Signal Word DANGER SECTION 2 — HAZARDS IDENTIFICATION Hazard class: Acute toxicity, oral (Category 4). 0000000976 00000 n trailer Product:)Ammonium)Hydroxide,)50%)v/v) RevisionDate:)05/18/2016) 6/7) Ecotoxicological Data: Water: Not applicable. 0000007425 00000 n Ammonia reacts with strong oxidizers, acids, halogens (including chlorine bleach), and salts of silver, zinc, copper, and other heavy metals. 0 colorless liquid with a strong odor and bad taste, Four Steps to Conducting a Job Safety Analysis in the Canadian Workplace, Train over any hazardous chemicals that employees may be exposed to, Train employees to detect and respond … Section 3: Composition / Information on Ingredients Ammonium Hydroxide, (1336-21-6), 1-2% as Ammonia Water: (CAS No. Strong oxidizers, acids, halogens, salts of silver & zinc [Note: Corrosive to copper & galvanized surfaces.] For small fires, use dry chemical, carbon dioxide, water spray or alcohol-resistant foam extinguishers. endobj /Producer(Sub Systems, Inc.)/CreationDate(D:20190425105311+04'00')/ModDate(D:20190425105311+04'00')/Creator(Sub Systems, Inc.) {�k��Ο�(���(�?�s_���/C�V��0�ਇm�l8a���;�����•|�1�3m����3~N�֙���y����4�?�4�[��JEL�. Ammonia (H3N) is a gas. xref §ðÔ¶ËÞTšz͑W®,£ùž¥Ö˜›‹%|$f‘F”ØßÌßznÅO§Cƒ¬!š¥ÿ£TehXãpýÁ©/yþô@=rÚ >> Safety Data Sheet (SDS) SECTION 1 — CHEMICAL PRODUCT AND COMPANY IDENTIFICATION Ammonium Hydroxide 1.1 M - 14.8 M Flinn Scientific, Inc. P.O. Direct contact with the eyes can cause blindness if not washed away immediately within the first 10 seconds. Ammonium hydroxide is a caustic inorganic base (an alkaline substance). PRODUCT AND COMPANY IDENTIFICATION Product name: Ammonium Hydroxide ~30% Product code: 05870-16 Supplier: StatLab Medical Products 2090 Commerce Drive McKinney, TX 75069 800-442-3573 972-436-1369 Fax statlab.com Synonym: None. fExposure can irritate the eyes, nose and throat. Concentrated solution violent to explosive reaction with many compounds e.g. Search results for 1336-21-6 at Sigma-Aldrich. ý„da BL:†nCò“é [Ö ×-|ëúÀ7LôÿDÄÛÚVíp)J0æs~t@û‘ãä˜ñVÖêg,0G'¹ ¬bÎm™Ë–õ•@ÅëæåºS› ª‚ÕÛò‹å0†(ĀxÁX,C­Ý ü¥F$°üšÿÛ Other Hazards Ammonium hydroxide is very volatile and may release ammonia as a gas. "R}~Q:~pgg'������"���l���/���������O�:OϽV�ޞ�~ @����������zo��“7��g;)�Kߜӗ���;�����=�d�������'}z��8}����7w�7?���I�������u��w?ݾw��~�����i�����k���K�^��^'��d4k����˗;�g����_�u_�������L��OC6���($uiz["��Dڻw�#�޽���6����"������UH��8/�?CZ7�����D|z�?���W5M��78����k"^�8�ö����$���p(�?kӴ������ׅL�}��~�Gm�ֽ�{{���>~�O4��v���{���x��?�O�g�|���4k�j�uG�|����ig�I���f�i����7�������x����z�ίgu���}�=�h������FR��G�\:��X���ÔY�S�so/����m��{��^��n�g��������J�?�_����˝��l��R�� ~ ������!J�����s��A���'Y*��ߤ\=���f/�� ��3[��= ����'u~ͻ�/���g�����i���� �_C�|�2��S�A^�����|z��;���^���jy�h>~�� ��{�7? P273 - Avoid release to the environment. Molecular Weight 35.05 . On heating: release of toxic/corrosive/combustible gases/vapour s (ammonia). 28 0 obj <> endobj 0000015924 00000 n Reacts with aqueous silver nitrate sodium hydroxide to give a black precipitate of silver nitride. Ammonia solution, also known as ammonia water, ammonium hydroxide, ammoniacal liquor, ammonia liquor, aqua ammonia, aqueous ammonia, or (inaccurately) ammonia, is a solution of ammonia in water. May adversely affect pH of aquatic ecosystems. 0000003112 00000 n The gas is an eye, skin and respiratory irritant. 0000003612 00000 n 0000006041 00000 n 0000006391 00000 n PRODUCT AND COMPANY IDENTIFICATION Product Name: Ammonium Hydroxide 3N Synonyms/Generic Names: Aqueous Ammonia; Strong Ammonia Solution; Stronger Ammonia Water Product Number: 8133 Product Use: Industrial, Manufacturing or Laboratory use Manufacturer: Columbus Chemical Industries, Inc. 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